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F3629

Sigma-Aldrich

Ammonium iron(III) sulfate dodecahydrate

ReagentPlus®, ≥99%

Synonym(s):

Ammonium iron disulfate dodecahydrate, Ammonium ferric sulfate dodecahydrate

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250 G
€30.50
500 G
€53.00

About This Item

Linear Formula:
NH4Fe(SO4)2 · 12H2O
CAS Number:
Molecular Weight:
482.19
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

€30.50


Please contact Customer Service for Availability

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product line

ReagentPlus®

Assay

≥99%

reaction suitability

core: iron
reagent type: catalyst

mp

39-41 °C (lit.)

storage temp.

2-8°C

SMILES string

N.O.O.O.O.O.O.O.O.O.O.O.O.[Fe+3].OS([O-])(=O)=O.[O-]S([O-])(=O)=O

InChI

1S/Fe.H3N.2H2O4S.12H2O/c;;2*1-5(2,3)4;;;;;;;;;;;;/h;1H3;2*(H2,1,2,3,4);12*1H2/q+3;;;;;;;;;;;;;;;/p-3

InChI key

LCPUDZUWZDSKMX-UHFFFAOYSA-K

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Application

Ammonium iron(III) sulfate dodecahydrate can be used as:
  • A catalyst to synthesize 1,4-dihydropyridines via one-pot three-component condensation reaction of dimedone, aldehydes, and 3-aminocrotonate in ethanol.
  • An additive in the reduction of aromatic nitro compounds to the corresponding amino compounds in the presence of alumina-supported hydrazine hydrate as a catalyst.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Dam. 1

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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R Săndulescu et al.
Journal of pharmaceutical and biomedical analysis, 14(8-10), 951-958 (1996-06-01)
The method is based upon the reaction between fluoride ions and the coloured complex of Fe(III) with methyl salicylate to form the stable, colourless hexaflouride complex of iron. The conditions of the method (pH, time and combination ratio) were studied
Steven Babic et al.
Physics in medicine and biology, 53(6), 1637-1650 (2008-03-28)
Freshly prepared radiochromic ferrous xylenol-orange (FX) gels optically scanned with a light source exhibit a threshold dose response that is thermally and wavelength dependent. Correction for this threshold dose leads to accurate dose calibration and better reproducibility in multiple fraction
J G Reinhold et al.
The Journal of nutrition, 116(6), 1007-1017 (1986-06-01)
The effects of pH, ascorbate, citrate and dietary fiber on retention of ferrous and ferric iron by jejuno-ileal segments of rat intestine were examined in vivo. Iron was introduced in an isosmotic solution of sodium chloride and dextrose buffered by
Andrew J Ghio et al.
American journal of physiology. Lung cellular and molecular physiology, 283(3), L563-L572 (2002-08-10)
The iron chelator deferoxamine has been reported to inhibit both xanthine oxidase (XO) and xanthine dehydrogenase activity, but the relationship of this effect to the availability of iron in the cellular and tissue environment remains unexplored. XO and total xanthine
I Wittmann et al.
Chemico-biological interactions, 138(2), 171-187 (2001-10-24)
Diabetes mellitus is characterized by increased methylglyoxal (MG) production. The aim of the present study was to investigate the role of iron in the cellular and molecular effects of MG. A red blood cell (RBC) model and L-arginine were used

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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