934542
Silyl-ether based ROMP Monomer
PhSi
Synonym(s):
2,2-Diphenyl-1,3-dioxa-2-silacyclooct-5-ene
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About This Item
Empirical Formula (Hill Notation):
C17H18O2Si
CAS Number:
Molecular Weight:
282.41
UNSPSC Code:
12162002
NACRES:
NA.21
Pricing and availability is not currently available.
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Assay
≥98%
Quality Level
form
powder or crystals
composition
PhSi
color
off-white to light yellow
SMILES string
C1([Si]2(C3=CC=CC=C3)OC/C=C\CCO2)=CC=CC=C1
InChI key
AVFOQRQHJSIDGD-BAQGIRSFSA-N
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General description
Ring opening metathesis polymerization (ROMP) monomers are attractive building block for advanced polymeric materials in the biomedical field. 2,2-Diphenyl-1,3-dioxa-2-silacyclooct-5-ene, or the silyl ether based ROMP monomer PhSi, is a bifunctional cyclic olefin that can be used to synthesize a variety of macromolecules and polymers with diverse compositions and complex structures. PhSi can copolymerize with a variety of norbornene derivatives including small molecules and macromolecules, enabling the formation of backbone-degradable copolymers that can be used in a variety of biomedical applications. The ROMP polymerization method is superior as it permits the tailorability of the resulting polymer material.
Application
Synthesis of advanced polymeric materials for biomedical applications including:
- drug delivery
- molecular imaging
- self assembly
- hydrogels
- medical device coatings
- stimuli responsive material
Features and Benefits
- Copolymerize efficiency with a wide variety of norbornene-based (macro)monomers
- Controlled ROMP polymerization
- Silyl ether substitute can be tuned to control degradation
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Product No.
Description
Pricing
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Scott C Radzinski et al.
Macromolecular rapid communications, 37(7), 616-621 (2016-02-06)
Bottlebrush polymers are synthesized using a tandem ring-opening polymerization (ROP) and ring-opening metathesis polymerization (ROMP) strategy. For the first time, ROP and ROMP are conducted sequentially in the same pot to yield well-defined bottlebrush polymers with molecular weights in excess
Banruo Huang et al.
Journal of the American Chemical Society, 143(43), 17920-17925 (2021-10-23)
Materials capable of degradation upon exposure to light hold promise in a diverse range of applications including biomedical devices and smart coatings. Despite the rapid access to macromolecules with diverse compositions and architectures enabled by ring-opening metathesis polymerization (ROMP), a
Peyton Shieh et al.
Nature chemistry, 11(12), 1124-1132 (2019-10-30)
Ring-opening metathesis polymerization of norbornene-based (macro)monomers is a powerful approach for the synthesis of macromolecules with diverse compositions and complex architectures. Nevertheless, a fundamental limitation of polymers prepared by this strategy is their lack of facile degradability, limiting their utility
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