667811
(−)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane
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About This Item
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form
solid
Quality Level
mp
143-147 °C
functional group
phenyl
phosphine
SMILES string
C1C[C@@H](P(CCP2[C@H](CC[C@@H]2c3ccccc3)c4ccccc4)[C@H]1c5ccccc5)c6ccccc6
InChI
1S/C34H36P2/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30/h1-20,31-34H,21-26H2/t31-,32-,33-,34-/m1/s1
InChI key
VHHAZLMVLLIMHT-YFRBGRBWSA-N
Related Categories
Application
(−)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane can be used:
- As a chiral ligand in the 1,3-dipolar cycloaddition reaction of azomethyne yielded [70]fullerene enantiomers; catalyzed by silver.
- As a component of the catalytic system along with silver, which is used for the synthesis of fullerene hybrids.
Legal Information
Sold in collaboration with Namena Corp. for research purposes only.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Find documentation for the products that you have recently purchased in the Document Library.
Stereodivergent-at-Metal Synthesis of [60] Fullerene Hybrids
Angewandte Chemie (International Edition in English), 56(8), 2136-2139 (2017)
Hierarchical Selectivity in Fullerenes: Site-, Regio-, Diastereo-, and Enantiocontrol of the 1, 3-Dipolar Cycloaddition to C70
Angewandte Chemie (International Edition in English), 50(27), 6060-6064 (2011)
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