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549495

Sigma-Aldrich

(R)-(+)-1,1-Diphenyl-2-aminopropane

97%

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About This Item

Empirical Formula (Hill Notation):
C15H17N
CAS Number:
Molecular Weight:
211.30
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

optical activity

[α]20/D +16°, c = 1 in chloroform

mp

77-80 °C (lit.)

functional group

amine
phenyl

SMILES string

C[C@@H](N)C(c1ccccc1)c2ccccc2

InChI

1S/C15H17N/c1-12(16)15(13-8-4-2-5-9-13)14-10-6-3-7-11-14/h2-12,15H,16H2,1H3/t12-/m1/s1

InChI key

XNKICCFGYSXSAI-GFCCVEGCSA-N

Application

(R)-(+)-1,1-Diphenyl-2-aminopropane can be used as a precursor for the preparation of trisubstituted dihydroisoquinoline derivatives via Bischler-Napieralski reaction.

Legal Information

Product of Onyx Scientific, U.K.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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The asymmetric Bischler-Napieralski reaction: preparation of 1, 3, 4-trisubstituted 1, 2, 3, 4-tetrahydroisoquinolines
Nicoletti M, et al.
Journal of the Chemical Society. Perkin Transactions 1, 116-121 (2002)

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