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Key Documents

331406

Sigma-Aldrich

cis-Dichlorobis(triethylphosphine)platinum(II)

98%

Synonym(s):

(Et3P)2PtCl2, cis-Bis(triethylphosphine)platinum dichloride

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About This Item

Linear Formula:
[(C2H5)3P]2PtCl2
CAS Number:
Molecular Weight:
502.30
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

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Quality Level

Assay

98%

form

powder

reaction suitability

core: platinum
reagent type: catalyst

mp

193-194 °C (lit.)

SMILES string

Cl[Pt]Cl.CCP(CC)CC.CCP(CC)CC

InChI

1S/2C6H15P.2ClH.Pt/c2*1-4-7(5-2)6-3;;;/h2*4-6H2,1-3H3;2*1H;/q;;;;+2/p-2

InChI key

WPWLTKRUFHHDLP-UHFFFAOYSA-L

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Questions

  1. For product number 331406, is the PCH2CH3 group linked to Pt via a chemical bond or a coordination bond? Additionally, concerns about its stability arise with the addition of NaSCN to a water system. Is there a risk of SCN- displacing the PCH2CH3 group?

    1 answer
    1. In the complex for product number 331406, the PCH2CH3 group is bound to platinum through a coordination bond. This bond is formed by the two electrons of the lone pair on phosphorus coordinating to the metal center. While it is a type of chemical bond, the term "coordination bond" is the most accurate description.
      Regarding stability with the addition of NaSCN in a water system, the SCN- ion, being negatively charged, would more likely replace negatively charged ligands, such as chlorides, to maintain the compound's neutrality, rather than the neutral phosphine ligand. However, without specific familiarity with SCN ions' reactivity, it cannot be definitively stated whether SCN- would preferentially bind to platinum over chloride.

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