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143995

Sigma-Aldrich

Propargyl chloride

98%

Synonym(s):

3-Chloro-1-propyne

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€38.50
25 G
€97.70

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5 G
€38.50
25 G
€97.70

About This Item

Linear Formula:
HC≡CCH2Cl
CAS Number:
624-65-7
Molecular Weight:
74.51
Beilstein:
506005
EC Number:
210-856-9
MDL number:
MFCD00000980
UNSPSC Code:
12352100
PubChem Substance ID:
24848620
NACRES:
NA.22

€38.50

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Quality Level

100

Assay

98%

form

liquid

refractive index

n20/D 1.435 (lit.)

bp

58 °C (lit.)

solubility

benzene: miscible
chloroform: miscible
diethyl ether: miscible
ethanol: miscible
ethyl acetate: miscible
ethylene glycol: miscible
water: insoluble

density

1.03 g/mL at 25 °C (lit.)

functional group

alkyl halide
chloro

storage temp.

2-8°C

SMILES string

ClCC#C

InChI

1S/C3H3Cl/c1-2-3-4/h1H,3H2

InChI key

LJZPPWWHKPGCHS-UHFFFAOYSA-N

General description

Propargyl chloride is an efficient propargylating agent[1]. It generates propargyl radicals by the pulsed laser photolysis[2].

Application

Propargyl chloride was used to study emission spectra of dissociating propargyl chloride upon photoexcitation at 199 nm[3]. It was used in the synthesis of novel tetraaryl analog of bisphenol A and triaryl analog of bisphenol A propargyl resins[4].

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Oral - Flam. Liq. 2 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

66.2 °F - closed cup

Flash Point(C)

19 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT3724
MKCQ6303
MKCQ1519
MKCK8550
MKCK0549

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Investigating the C-Cl Antibonding Character in the pp* Excited State of Vinyl, Allyl, and Propargyl Chloride: Emission Spectra and ab Initio Calculations.
Browning PW, et al.
The Journal of Physical Chemistry, 100(19), 7765-7771 (1996)
DIPROPARGYL ETHERS OF HIGH ASPECT RATIO BISPHENOLS.
Filipova TS, et al.
Polymer Preprints (American Chemical Society, Division of Polymer Chemistry), 48(1), 388-388 (2007)
Akira Matsugi et al.
The journal of physical chemistry. A, 115(26), 7610-7624 (2011-05-24)
The kinetics and mechanisms of the self-reaction of allyl radicals and the cross-reaction between allyl and propargyl radicals were studied both experimentally and theoretically. The experiments were carried out over the temperature range 295-800 K and the pressure range 20-200
Lyudmila A Grischenko et al.
Carbohydrate research, 376, 7-14 (2013-06-04)
New arabinogalactan propargyl ethers with degree of substitution (DS) up to 2.8 have been obtained by propargylation of arabino-3,6-galactan (AG) with propargyl bromide (PB) in the two-phase system 30-60% КОН aqueous solution/toluene in the presence of triethylbenzylammonium chloride (TEBAС) or

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