- Suzuki-Miyaura cross-couplings of secondary allylic boronic esters.
Suzuki-Miyaura cross-couplings of secondary allylic boronic esters.
Chemical communications (Cambridge, England) (2011-12-20)
Ben W Glasspoole, Kazem Ghozati, Jonathon W Moir, Cathleen M Crudden
PMID22179308
ABSTRACT
Palladium-catalyzed cross-coupling reactions of secondary allylic boronic esters with iodoarenes were demonstrated under the conditions previously described for the coupling of benzylic substrates. The regioselectivity of the process was largely dictated by the pattern of olefin substitution.
MATERIALS