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Key Documents

M9635

Sigma-Aldrich

Microperoxidase (MP-9) ammonium salt from equine heart cytochrome c

~90% (HPLC)

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About This Item

Empirical Formula (Hill Notation):
C74H99FeN17O18S2
CAS Number:
Molecular Weight:
1634.66
MDL number:
UNSPSC Code:
12352204
PubChem Substance ID:

assay

~90% (HPLC)

storage temp.

−20°C

SMILES string

N.CC(C)C(NC(=O)C(NC(=O)C(Cc1cnc[nH]1)NC(=O)C2CSC(C)C3=C(C)C4=CC5=[N]6C(=Cc7c(CCC(O)=O)c(C)c8C=C9C(C(C)SCC(N)C(=O)NC(C)C(=O)NC(CCC(N)=O)C(=O)N2)=C(C)C%10=[N]9[Fe]6(N4C3=C%10)n78)C(CCC(O)=O)=C5C)C(C)O)C(=O)NC(CCC(O)=O)C(=O)NC(CCCCN)C(O)=O

InChI

1S/C74H101N17O18S2.Fe.H3N/c1-32(2)64(72(106)86-46(17-21-61(98)99)68(102)87-47(74(108)109)13-11-12-22-75)90-73(107)65(38(8)92)91-70(104)56(23-41-28-78-31-79-41)88-71(105)57-30-111-40(10)63-35(5)50-24-48-33(3)42(14-19-59(94)95)52(81-48)27-53-43(15-20-60(96)97)34(4)49(82-53)25-54-62(36(6)51(84-54)26-55(63)83-50)39(9)110-29-44(76)67(101)80-37(7)66(100)85-45(69(103)89-57)16-18-58(77)93;;/h24-28,31-32,37-40,44-47,56-57,64-65,92H,11-23,29-30,75-76H2,1-10H3,(H17,77,78,79,80,81,82,83,84,85,86,87,88,89,90,91,93,94,95,96,97,98,99,100,101,102,103,104,105,106,107,108,109);;1H3/q;+2;/p-2/b48-24-,49-25-,50-24-,51-26-,52-27-,53-27-,54-25-,55-26-;;

InChI key

SOIPPMUJPJAVPO-JTUAPZFOSA-L

Application

Of possible interest as a heme tracer in electron microscopic cytochemistry.

Biochem/physiol Actions

Has peroxidase activity.

Other Notes

The proposed structure is the heme portion of cytochrome c with amino acids 14 through 22 still attached.

Preparation Note

Prepared by enzymatic degradation.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


Certificates of Analysis (COA)

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A heme-nonapeptide tracer for electron microscopy. Preparation, characterization and comparison with other heme-tracers.
H Plattner et al.
Histochemistry, 53(3), 223-242 (1977-08-22)

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