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40559

Sigma-Aldrich

3-Piperonylcyclobutanone

≥98.0% (HPLC)

Synonym(s):

3-(1,3-Benzodioxol-5-ylmethyl)cyclobutanone, 3-(3,4-Methylenedioxybenzyl)cyclobutanone

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About This Item

Empirical Formula (Hill Notation):
C12H12O3
CAS Number:
157020-88-7
Molecular Weight:
204.22
MDL number:
MFCD01570993
UNSPSC Code:
12352200
PubChem Substance ID:
329756003
NACRES:
NA.25

assay

≥98.0% (HPLC)

form

liquid

SMILES string

O=C1CC(C1)Cc2ccc3OCOc3c2

InChI

1S/C12H12O3/c13-10-4-9(5-10)3-8-1-2-11-12(6-8)15-7-14-11/h1-2,6,9H,3-5,7H2

InChI key

AWAOUJUBBHDZRM-UHFFFAOYSA-N

Application

3-Piperonylcyclobutanone may be used as a reagent in the chiral synthesis of lignan lactones such as (-)-hinokinin, (-)-deoxypodorhizone, (-)-isohibalactone and (-)-savinin.

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

Certificates of Analysis (COA)

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Chiral synthesis of lignan lactones, (?)-hinokinin, (?)-deoxypodorhizone, (?)-isohibalactone and (?)-savinin by means of enantioselective deprotonation strategy.
Toshio Honda, Nobuaki Kimura,
Journal of the Chemical Society. Perkin Transactions 1, 1, 1043-1046 (1994)

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