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83352

Sigma-Aldrich

Mercury(II) acetate

puriss. p.a., ACS reagent, ≥99.0% (precipitation titration)

Synonym(s):

Mercuric acetate

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50 G
$144.00
250 G
$509.00

About This Item

Linear Formula:
(CH3COO)2Hg
CAS Number:
Molecular Weight:
318.68
Beilstein/REAXYS Number:
3563831
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NB.24
assay:
≥99.0% (precipitation titration)
form:
powder or crystals
solubility:
water: soluble(lit.)

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grade

ACS reagent
puriss. p.a.

assay

≥99.0% (precipitation titration)

form

powder or crystals

ign. residue (after reduction)

≤0.02%

mp

179-182 °C (lit.)

solubility

water: soluble(lit.)

anion traces

chloride (Cl-): ≤50 mg/kg
nitrate (NO3-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤10 mg/kg
Hg+: ≤4000 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg

SMILES string

CC(=O)O[Hg]OC(C)=O

InChI

1S/2C2H4O2.Hg/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

BRMYZIKAHFEUFJ-UHFFFAOYSA-L

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General description

Mercury(II) acetate forms various addition compounds with olefins. Polarographic evaluation of these addition compounds has been proposed.[1] It participates in the synthesis of nitrate esters, acetate esters, alcohols and ethers.[2]

Application

Mercury(II) acetate may be used in the preparation of 2-benzylidene-3(2H)-benzofuran-3-ones (aurones).[3]

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Polarography of olefin-mercury (II) acetate addition compounds.
Fleet B and Jee RD.
Journal of Electroanalytical Chemistry, 25(3), 397-408 (1970)
Mercury-assisted solvolyses of alkyl halides: Simple procedures for the preparation of nitrate esters, acetate esters, alcohols and ethers.
McKillop A and Ford ME.
Tetrahedron, 30(15), 2467-2475 (1974)
Synthesis of 2-benzylidene-3 (2H)-benzofuran-3-ones (aurones) by oxidation of 2'-hydroxychalcones with mercury (II) acetate.
Sekizaki H.
Bulletin of the Chemical Society of Japan, 61(4), 1407-1409 (1988)
G Gellerstedt et al.
Carbohydrate research, 294, 41-51 (1996-11-20)
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