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239313

Sigma-Aldrich

Sodium sulfate

ACS reagent, ≥99.0%, anhydrous, granular

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About This Item

Linear Formula:
Na2SO4
CAS Number:
Molecular Weight:
142.04
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent
anhydrous

assay

≥99.0%

form

granular

impurities

≤0.01% insolubles
≤5 ppm N compounds

loss

≤0.5% loss on ignition

pH

5.2-9.2 (25 °C, 5%)

mp

884 °C (lit.)

density

2.68 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.001%
phosphate (PO43-): ≤0.001%

cation traces

Ca: ≤0.01%
Fe: ≤0.001%
K: ≤0.01%
Mg: ≤0.005%
heavy metals: ≤5 ppm (by ICP-OES)

storage temp.

room temp

SMILES string

[Na+].[Na+].[O-]S([O-])(=O)=O

InChI

1S/2Na.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2

InChI key

PMZURENOXWZQFD-UHFFFAOYSA-L

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Application

Sodium sulfate (anhydrous) can be used as a catalyst in the synthesis of 1,3-diaryl-2-propen-1-one oxime by condensation of 1,3-diaryl-2-propen-1-one with hydroxylamine hydrochloride in ethanol.
NaSO4 can also be used as a drying agent in organic synthesis for the removal of traces of water from organic extracts. It is used for drying almost all compounds including fatty acids, aldehydes, ketones, and alkyl and aryl halogenides.

Legal Information

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Silveira EV, et al.
Industrial Crops and Products, 97, 545-551 (2017)
Synthesis of 3-and 5-Alkyl-6-alkyl (aryl) tetrahydropyran-2, 4-diones by the Condensation of ?-Oxo Acid Esters with Aldehydes and Ketones
Lokot, IP, et al.
Chemistry of Heterocyclic Compounds, 37(6), 707-714 (2001)
Improved Synthesis of 1, 3-Diaryl-2-propen-1-one Oxime in the Presence of Anhydrous Sodium Sulfate
Xu Xiaoya, et al.
Chin. J. Chem., 29(12), 2781-2784 (2011)
Eagleson M.
Concise Encyclopedia Chemistry, 405-405 (1994)
How does sodium sulfate crystallize? Implications for the decay and testing of building materials.
Rodriguez-Navarro C, et al.
Cement and Concrete Research, 30(10), 1527-1534 (2000)

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