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210021

Sigma-Aldrich

Hydriodic acid

57 wt. % in H2O, distilled, stabilized, 99.95%

Synonym(s):

Hydriotic acid

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About This Item

Empirical Formula (Hill Notation):
HI
CAS Number:
Molecular Weight:
127.91
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.21

Quality Level

assay

99.95%

form

liquid

contains

<1.5% hypophosphorous acid as stabilizer

concentration

57 wt. % in H2O

bp

127 °C (lit.)

density

1.701 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

I

InChI

1S/HI/h1H

InChI key

XMBWDFGMSWQBCA-UHFFFAOYSA-N

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General description

Hydriodic acid (HI) along with red phosphorus (HI/red P) plays the role of a reducing agent for the preparation of methamphetamine. HI/Phosphorous causes the reduction of various polycyclic quinones. HI also participates as a reducing agent for the conversion of various polyarene quinones, hydroquinones and phenols to the corresponding aromatic hydrocarbons.
Hydriodic acid is hydrogen iodide gas dissolved in water. It is a strong acid generally used as a reducing agent.

Application

Hydriodic acid may be used as a reagent for the conversion of fatty alcohols and glyceryl ethers to alkyl iodides.

pictograms

CorrosionEnvironment

signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

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Studies on the composition of glyceryl ethers and their preparation from diacyl glyceryl ethers in liver oils.
Guyer KE, et al.
Journal of Lipid Research, 4(4), 385-391 (1963)
Efficient reduction of polycyclic quinones, hydroquinones, and phenols with hydriodic acid.
Konieczny M and Harvey RG.
The Journal of Organic Chemistry, 44(26), 4813-4816 (1979)
Relationships between circulating and intracellular thyroid hormones: physiological and clinical implications.
P R Larsen et al.
Endocrine reviews, 2(1), 87-102 (1981-01-01)
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