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60607

Sigma-Aldrich

Potassium trimethylsilanolate

technical, ≥90% (NT)

Synonym(s):

Trimethylsilanol potassium salt

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About This Item

Linear Formula:
(CH3)3SiOK
CAS Number:
10519-96-7
Molecular Weight:
128.29
Beilstein/REAXYS Number:
3560282
EC Number:
234-062-7
MDL number:
MFCD00013421
UNSPSC Code:
12352000
PubChem Substance ID:
329759102

grade

technical

assay

≥90% (NT)

mp

135-138 °C (lit.)

SMILES string

[K+].C[Si](C)(C)[O-]

InChI

1S/C3H9OSi.K/c1-5(2,3)4;/h1-3H3;/q-1;+1

InChI key

LBKJNHPKYFYCLL-UHFFFAOYSA-N

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Description
Pricing

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Diane M Coe et al.
Organic & biomolecular chemistry, 1(7), 1106-1111 (2003-08-21)
A convenient and efficient method for the cleavage of 1,3-oxazolidin-5-ones and 1,3-oxazolidin-2-ones utilising potassium trimethylsilanolate in tetrahydrofuran is described. The benzyloxycarbonyl-protecting group is readily removed under the reaction conditions, whereas the N-benzoyl group is stable. A synthesis of (R)-salmeterol exploiting
Fabricio A Hansel et al.
Rapid communications in mass spectrometry : RCM, 25(13), 1893-1898 (2011-06-04)
A methodology is presented for the determination of dihydroxy fatty acids preserved in the 'bound' phase of organic residues preserved in archaeological potsherds. The method comprises saponification, esterification, silica gel column chromatographic fractionation, and analysis by gas chromatography/mass spectrometry. The
E N M Ho et al.
Analytica chimica acta, 586(1-2), 208-216 (2007-03-28)
Turinabol (4-chloro-17alpha-methyl-17beta-hydroxy-1,4-androstadien-3-one) is a synthetic oral anabolic androgenic steroid. As in the case of other anabolic steroids, it is a prohibited substance in equine sports. The metabolism of turinabol in human has been reported previously; however, little is known about
Grzegorz Piechota et al.
Bioresource technology, 103(1), 16-20 (2011-10-29)
The removal and determination of trimethylsilanol (TMSOH) in landfill gas has been studied before and after the special E3000-ITC System. The system works according to principle of temperature swing. The performance of TMSOH and humidity removal was 20% and more
D M Hui et al.
Clinica chimica acta; international journal of clinical chemistry, 302(1-2), 171-188 (2000-11-14)
We developed a new assay method for fluoride anion (F(-)) a specific metabolite of sarin. Trimethyifluorosilane (TMFS) was derivatized from F(-) with trimethylsilanol, and TMFS was detected with a GC-flame ionization detector (FID) and capillary column system. The linear range
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