This solution was very expensive and did not work very well. Making-up the Brady's solution from solid using the methanol recipe works much, much better. Unfortunately the solid is unavailable at the moment.
42215
2,4-Dinitrophenylhydrazine Phosphoric acid solution
2,4-Dinitrophenylhydrazine Phosphoric acid solution
1 of 1 reviewers received a sample product or took part in a promotion
for derivatization (of aldehydes and ketones), LiChropur™, substitute for the explosive solid, ~0.2 M (~4%)
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About This Item
Empirical Formula (Hill Notation):
C6H6N4O4
CAS Number:
Molecular Weight:
198.14
Beilstein/REAXYS Number:
6258433
MDL number:
UNSPSC Code:
41116105
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
grade
for derivatization (of aldehydes and ketones)
form
liquid
quality
LiChropur™
composition
2,4-dinitrophenylhydrazine
ethanol
phosphoric acid
concentration
~0.2 M (~4%)
technique(s)
thin layer chromatography (TLC): suitable
density
1.35 g/mL at 20 °C
SMILES string
OP(O)(O)=O.NNc1ccc(cc1[N+]([O-])=O)[N+]([O-])=O
InChI
1S/C6H6N4O4.H3O4P/c7-8-5-2-1-4(9(11)12)3-6(5)10(13)14;1-5(2,3)4/h1-3,8H,7H2;(H3,1,2,3,4)
InChI key
RYSWHUOYGUCXQB-UHFFFAOYSA-N
Application
- Visible-light excitable Eu(3+)-induced hyaluronic acid-chitosan aggregates with heterocyclic ligands for sensitive and fast recognition of hazardous ions: Utilizes 1,10-phenanthroline monohydrate in environmental sensing applications to detect hazardous ions efficiently (Aleem AR, Ding W, Liu J, Li T, Guo Y, Wang Q, Wang Y, Rehman FUL, Kipper MJ, Belfiore LA, Tang J, 2021).
- Structural diversity of copper(I) complexes formed by pyrrole- and dipyrrolylmethane-based diphosphine ligands with cu-X···HN hydrogen bonds: Researches the coordination chemistry of 1,10-phenanthroline monohydrate, highlighting its role in forming novel copper(I) complexes (Kumar S, Mani G, Dutta D, Mishra S, 2014).
- Direct electron transfer from glucose oxidase immobilized on polyphenanthroline-modified glassy carbon electrode: Demonstrates the use of 1,10-phenanthroline monohydrate in biosensor applications for direct electron transfer mechanisms (Oztekin Y, Ramanaviciene A, Yazicigil Z, Solak AO, Ramanavicius A, 2011).
Other Notes
Reagent for derivatizing aldehydes and ketones, replacement for the explosive solid[1]
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Met. Corr. 1 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
86.0 °F
flash_point_c
30 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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