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37032

Supelco

Senkirkine

analytical standard

Synonym(s):

12-Hydroxy-4-methyl-4,8-secosenecionan-8,11,16-trione, Renardine

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About This Item

Empirical Formula (Hill Notation):
C19H27NO6
CAS Number:
2318-18-5
Molecular Weight:
365.42
MDL number:
MFCD01684247
UNSPSC Code:
85151701
PubChem Substance ID:
329755593

grade

analytical standard

Quality Level

100

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

cleaning products
cosmetics
food and beverages
personal care

format

neat

storage temp.

−20°C

SMILES string

C\C=C1\C[C@@H](C)[C@@](C)(O)C(=O)OCC2=CCN(C)CC[C@@H](OC1=O)C2=O

InChI

1S/C19H27NO6/c1-5-13-10-12(2)19(3,24)18(23)25-11-14-6-8-20(4)9-7-15(16(14)21)26-17(13)22/h5-6,12,15,24H,7-11H2,1-4H3/b13-5-,14-6-/t12-,15-,19-/m1/s1

InChI key

HPDHKHMHQGCNPE-QLJRNOHWSA-N

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Reconstitution

Dried down, 50 μg/mL after reconstitution with 1 mL of water

pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

signalword

Danger

hcodes

H300,H341

Hazard Classifications

Acute Tox. 1 Oral - Muta. 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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M Bah et al.
Journal of ethnopharmacology, 43(1), 19-30 (1994-06-01)
A study of the hepatotoxic pyrrolizidine alkaloids (PAs) contained in Packera candidissima (Greene) Weber & Löve (Senecio candidissimus Greene), a Mexican medicinal plant used for the treatment of kidney ailments and noted for its antiseptic properties, is reported. Analysis by
Senkirkine.
IARC monographs on the evaluation of the carcinogenic risk of chemicals to humans, 31, 231-238 (1983-07-01)
J A Glinski et al.
Acta crystallographica. Section C, Crystal structure communications, 44 ( Pt 9), 1593-1598 (1988-09-15)
lambda(Mo K alpha) = 0.71069 A, T = 298 K. Anonamine (I) (12,21-dihydroxy-4-methyl-4,8-secosenecionan-8,11,16-trione): C19H27NO7, Mr = 381.2, monoclinic, C2, a = 24.247 (7), b = 8.766 (2), c = 9.072 (1) A, beta = 99.21 (2) degrees, U = 1903.3
Xiao-Fang Guo et al.
Zhong yao cai = Zhongyaocai = Journal of Chinese medicinal materials, 34(5), 724-726 (2011-10-01)
To study alkaloids of Senecio scandens growing in Guangdong. The rapid resolution liquid chromatography-electrospray ionization mass spectrometry (RRLC-ESI-MS/MS) was used to analyse alkaloids of Senecio scandens growing in Guangdong, and senkirkine was isolated and purified by silica gel column chromatography.
E Roeder et al.
Natural toxins, 1(4), 241-245 (1993-01-01)
Two toxic pyrrolizidine alkaloids were isolated from Senecio leucanthemifolius and six from Senecio rodriguezii. Their structures were determined by spectroscopic methods.
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