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S5012

Sigma-Aldrich

Sodium hypophosphite monohydrate

≥99%

Synonym(s):

Sodium hypophosphite 1-hydrate, Sodiumphosphinite

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About This Item

Linear Formula:
NaH2PO2 · H2O
CAS Number:
10039-56-2
Molecular Weight:
105.99
EC Number:
231-669-9
MDL number:
MFCD06252379
UNSPSC Code:
12352302
PubChem Substance ID:
57654620
NACRES:
NA.22

assay

≥99%

form

powder, crystals or chunks

solubility

water: 100 mg/mL, clear, colorless

SMILES string

O.[Na+].[O-][PH2]=O

InChI

1S/Na.H3O2P.H2O/c;1-3-2;/h;3H2,(H,1,2);1H2/q+1;;/p-1

InChI key

PLZNPHDJGFDNRM-UHFFFAOYSA-M

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Application

Sodium hypophosphite monohydrate can be used as a:
  • Reducing agent in the synthesis of nickel nanoparticles (NiNP) from nickel acetate tetrahydrate under microwave irradiation.
  • Hydrogen donor in the enantioselective transfer hydrogenation of aliphatic and aromatic ketones to corresponding alcohols in presence of ruthenium catalyst.
  • Catalyst in esterification of spent grain to improve heavy metal ions adsorption capacity using N,N-dimethylformamide (DMF) as a solvent.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Fast esterification of spent grain for enhanced heavy metal ions adsorption.
Li Q, et al.
Bioresource Technology, 101(10), 3796-3799 (2010)
Microwave assisted greener synthesis of nickel nanoparticles using sodium hypophosphite.
Eluri R and Paul B
Materials Letters, 76, 36-39 (2012)
Biphasic Glycerol/2-MeTHF, Ruthenium-Catalysed Enantioselective Transfer Hydrogenation of Ketones Using Sodium Hypophosphite as Hydrogen Donor.
Guyon C, et al.
European Journal of Organic Chemistry, 2013(24), 5439-5444 (2013)
R Wadhwa et al.
Gerontology, 35(1), 14-18 (1989-01-01)
Addition of antioxidant, sodium hypophosphite (SHP; 1 mM), to the diet of Zaprionus paravittiger (Diptera) results in depressed ATPase activity in both the sexes in comparison to the normal group. However, the rate of age-related decline in ATPase activity is
W S Price et al.
Biophysical chemistry, 33(3), 205-215 (1989-07-01)
A 31P-NMR method, which complements earlier 13C-NMR procedures for probing the intra-erythrocyte microenvironment, is described. Hypophosphite is an almost unique probe of the erythrocyte microenvironment, since it is rapidly transported into the cell via the band 3 protein, and intra-
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