M33476

2-Methylbutyraldehyde

95%

• Synonym(s): α-Methyl-n-butanal, α-Methylbutanal, α-Methylbutyric aldehyde, (±)-2-Methylbutanal, 2-Ethylpropanal, 2-Formylbutane, 2-Methylbutanal
• Linear Formula: C₂H₅CH(CH₃)CHO
• CAS Number: 96-17-3
• Molecular Weight: 86.13
• Beilstein/REAXYS Number: 1633540
• EC Number: 202-485-6
• MDL number: MFCD00006984
• UNSPSC Code: 12352100
• PubChem Substance ID: 24896832
• NACRES: NA.22

Properties

• assay: 95%
• form: liquid
• refractive index: n20/D 1.3919 (lit.)
• bp: 90-92 °C (lit.)
• density: 0.806 g/mL at 20 °C; 0.804 g/mL at 25 °C (lit.)
• SMILES string: [H]C(=O)C(C)CC
• InChI: 1S/C5H10O/c1-3-5(2)4-6/h4-5H,3H2,1-2H3
• InChI key: BYGQBDHUGHBGMD-UHFFFAOYSA-N

Description

Application

2-Methylbutyraldehyde can be used as a reactant to synthesize:

• 2-amino-3-cyanopyridine derivatives via multicomponent condensation with various acetophenones and malononitrile in the presence of ammonium acetate.
• N,N-Diethyl-2-methyl-1-butanamine by reacting with diethylamine via Rh-catalyzed reductive amination reaction in the presence of molecular hydrogen.
• α-(2-Methylbutylidene)benzeneacetonitrile by condensation reaction with benzyl cyanide using tricyclic strong nonionic Lewis bases.

Safety Information

• pictograms: GHS02,GHS07,GHS09
• signalword: Danger
• hcodes: H225,H317,H319,H335,H411
• pcodes: P210 - P233 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Sens. 1 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 2
• flash_point_f: 23.0 °F
• flash_point_c: -5 °C
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter