776270

n-Propylmagnesium chloride solution

1.0 M in 2-methyltetrahydrofuran

• Synonym(s): Propylmagnesium chloride solution
• Linear Formula: CH₃CH₂CH₂MgCl
• CAS Number: 2234-82-4
• Molecular Weight: 102.85
• Beilstein/REAXYS Number: 3600246
• MDL number: MFCD00000474
• UNSPSC Code: 12352103
• PubChem Substance ID: 329767827
• NACRES: NA.22

Properties

• form: solution
• reaction suitability: reaction type: Grignard Reaction
• greener alternative product characteristics: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• concentration: 1.0 M in 2-methyltetrahydrofuran
• density: 0.896 g/mL at 25 °C
• greener alternative category: Aligned,
• SMILES string: CCC[Mg]Cl
• InChI: 1S/C3H7.ClH.Mg/c1-3-2;;/h1,3H2,2H3;1H;/q;;+1/p-1
• InChI key: AMXVKMXLDJXAPM-UHFFFAOYSA-M

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.

Application

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Packaging

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Safety Information

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H261,H302,H314
• pcodes: P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 2
• supp_hazards: EUH019
• Storage Class: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• wgk_germany: WGK 2
• flash_point_f: -22.0 °F - closed cup
• flash_point_c: -30 °C - closed cup