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743259

Sigma-Aldrich

1,3-Bis[(1S)-2,2-dimethyl-1-(1-naphthyl)propyl]imidazolinium iodide

≥96% (HPLC)

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About This Item

Empirical Formula (Hill Notation):
C33H39IN2
CAS Number:
Molecular Weight:
590.58
UNSPSC Code:
12352005
PubChem Substance ID:

assay

≥96% (HPLC)

form

powder

reaction suitability

reagent type: catalyst

impurities

≤1.0% water

SMILES string

[I-].CC(C)(C)[C@H](N1CC[N+](=C1)[C@@H](c2cccc3ccccc23)C(C)(C)C)c4cccc5ccccc45

InChI

1S/C33H39N2.HI/c1-32(2,3)30(28-19-11-15-24-13-7-9-17-26(24)28)34-21-22-35(23-34)31(33(4,5)6)29-20-12-16-25-14-8-10-18-27(25)29;/h7-20,23,30-31H,21-22H2,1-6H3;1H/q+1;/p-1/t30-,31+;

InChI key

FBAXFNUYKXNWGQ-USHPRDJASA-M

Application

Carbene ligand precursor

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Nakanishi, M.; et al.
Angewandte Chemie (International Edition in English), 50, 9775-9775 (2011)
Fused indolines by palladium-catalyzed asymmetric C-C coupling involving an unactivated methylene group.
Masafumi Nakanishi et al.
Angewandte Chemie (International ed. in English), 50(32), 7438-7441 (2011-07-05)

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