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737267

Sigma-Aldrich

Di(1-adamantyl)chlorophosphine

97%

Synonym(s):

Bis(1-adamantyl)phosphinous chloride, Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphinous chloride, Diadamantylchlorophosphine

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About This Item

Empirical Formula (Hill Notation):
C20H30ClP
CAS Number:
Molecular Weight:
336.88
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22

assay

97%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

impurities

may contain ≤1% CCl4

mp

168-173 °C

functional group

phosphine

SMILES string

ClP([C@]12C[C@H]3C[C@H](C[C@H](C3)C1)C2)[C@]45C[C@H]6C[C@H](C[C@H](C6)C4)C5

InChI

1S/C20H30ClP/c21-22(19-7-13-1-14(8-19)3-15(2-13)9-19)20-10-16-4-17(11-20)6-18(5-16)12-20/h13-18H,1-12H2/t13-,14+,15-,16-,17+,18-,19-,20-

InChI key

BVOJCPQWSXCCKU-RWTPHSKKSA-N

signalword

Danger

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Ozone 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1 - STOT RE 2 Inhalation - Water-react 3

target_organs

Liver,Kidney

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

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