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715050

Sigma-Aldrich

Chloro(tricyclohexylphosphine)gold(I)

97%

Synonym(s):

(Tricyclohexylphosphine)gold(I) chloride

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About This Item

Empirical Formula (Hill Notation):
C18H33AuClP
CAS Number:
Molecular Weight:
512.85
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:

assay

97%

form

solid

reaction suitability

core: gold
reagent type: catalyst

mp

218-222 °C

SMILES string

Cl[Au].C1CCC(CC1)P(C2CCCCC2)C3CCCCC3

InChI

1S/C18H33P.Au.ClH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h16-18H,1-15H2;;1H/q;+1;/p-1

InChI key

IBNPRSSHBVYHPU-UHFFFAOYSA-M

Application

Catalyst for:
  • Formal tandem bicyclizations of styrylindoles with alkynyl alkenones
  • Addition of X-H bonds to carbon-carbon multiple bonds
  • Arylation of pyrazine or pyridine with aryl bromides
  • Hydroarylation of alkenes with indoles
  • Cyclization
  • Hydroamination

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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