Skip to Content
MilliporeSigma
All Photos(1)

Key Documents

View All Documentation

710326

Sigma-Aldrich

(1,3-Dioxolan-2-ylmethyl)zinc bromide

0.6 M in THF

Sign Into View Organizational & Contract Pricing

Select a Size

50 ML
$398.50

$398.50

List Price$500.00Save 20%
Web-Only Promotion

Available to ship onApril 15, 2025Details

Request a Bulk Order
All Photos(1)

Select a Size

Change View
50 ML
$398.50

About This Item

Empirical Formula (Hill Notation):
C4H7BrO2Zn
Molecular Weight:
232.39
MDL number:
MFCD07698709
UNSPSC Code:
12352005
PubChem Substance ID:
329762915
NACRES:
NA.22

$398.50

List Price$500.00Save 20%
Web-Only Promotion

Available to ship onApril 15, 2025Details

Request a Bulk Order

form

liquid

Quality Level

100

reaction suitability

reaction type: C-C Bond Formation

concentration

0.6 M in THF

density

0.992 g/mL at 25 °C

functional group

ether

storage temp.

2-8°C

SMILES string

Br[Zn]CC1OCCO1

InChI

1S/C4H7O2.BrH.Zn/c1-4-5-2-3-6-4;;/h4H,1-3H2;1H;/q;;+1/p-1

InChI key

LOJRLQRGBKTHDB-UHFFFAOYSA-M

Related Categories

General description

(1,3-Dioxolan-2-ylmethyl)zinc bromide is an organozinc compound used as a reagent in Negishi cross-coupling reaction to prepare aryl or heteroaryl scaffolds via C-C bond formation.[1]

Application

(1,3-Dioxolan-2-ylmethyl)zinc bromide can be used as a reagent in the allylic alkylation reactions in the presence of iridium catalyst.[2]

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

-22.0 °F

flash_point_c

-30 °C

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
SHBR6264
SHBK8351
SHBF7227V
SHBD8067V
SHBD2485V

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Synthesis of 8-C-substituted 2, 6-diaminopurine acyclic nucleoside phosphonates by Negishi cross-coupling
Sedlavcek O, et al.
Collection of Czechoslovak Chemical Communications, 10(26), 449-450 (2015)
Iridium-Catalyzed Enantioselective Allylic Alkylation with Functionalized Organozinc Bromides
Hamilton JY, et al.
Angewandte Chemie (International ed. in English), 54(26), 7644-7647 (2015)

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service