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701742

Sigma-Aldrich

Copper(I) chloride - bis(lithium chloride) complex

1 M in THF

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50 ML
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50 ML
$209.00

About This Item

Linear Formula:
CuCl · 2LiCl
Molecular Weight:
183.79
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

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form

liquid

Quality Level

reaction suitability

core: copper
reagent type: catalyst

concentration

1 M in THF

refractive index

n20/D 1.442

density

1.015 g/mL at 25 °C

SMILES string

[Li]Cl.[Li]Cl.Cl[Cu]

InChI

1S/3ClH.Cu.2Li/h3*1H;;;/q;;;3*+1/p-3

InChI key

QJRAZNXUNZEAQH-UHFFFAOYSA-K

Application

Solution used in Cu(I) transmetallation for amination reaction[1][2]

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

62.6 °F

flash_point_c

17.0 °C


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Kienle, M. et al.
Synthesis, 1272-1272 (2007)
General preparation of primary, secondary, and tertiary aryl amines by the oxidative coupling of polyfunctional aryl and heteroaryl amidocuprates.
Vicente Del Amo et al.
Angewandte Chemie (International ed. in English), 45(46), 7838-7842 (2006-11-01)

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