698148

3-Nitrophenylboronic acid MIDA ester

97%

• Synonym(s): 6-Methyl-2-(3-nitrophenyl)-1,3,6,2-dioxazaborocane-4,8-dione
• Empirical Formula (Hill Notation): C₁₁H₁₁BN₂O₆
• CAS Number: 1311484-45-3
• Molecular Weight: 278.03
• MDL number: MFCD11215228
• UNSPSC Code: 12352103
• PubChem Substance ID: 329761985
• NACRES: NA.22

Properties

• assay: 97%
• form: powder
• mp: 211-215 °C
• SMILES string: CN1CC(=O)OB(OC(=O)C1)c2cccc(c2)[N+]([O-])=O
• InChI: 1S/C11H11BN2O6/c1-13-6-10(15)19-12(20-11(16)7-13)8-3-2-4-9(5-8)14(17)18/h2-5H,6-7H2,1H3
• InChI key: COEHPTUYNRXODY-UHFFFAOYSA-N

Description

Application

Suzuki Cross-Coupling with MIDA Boronates

3-Nitrophenylboronic acid MIDA ester is a stable boronic acid surrogate that can be used as a reagent in the Suzuki-Miyaura cross-coupling reactions to prepare useful building blocks via C-C bond formation. 3-allylnitrobenzene is one of the building blocks prepared from this ester by reacting with allyl bromide in the presence of a palladium catalyst.

Safety Information

• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)