693979

(1E,2E)-1,2-Bis(2,6-Diisopropylphenylimino)ethane

90%

• Synonym(s): N,N′-Bis(2,6-diisopropylphenyl)-1,4-diazabutadiene, N,N′-Bis(2,6-diisopropylphenyl)ethanediimine, Glyoxal bis(2,6-diisopropylanil)
• Linear Formula: (C₃H₇)₂C₆H₃NCHCHNC₆H₃(C₃H₇)₂
• CAS Number: 74663-75-5
• Molecular Weight: 376.58
• MDL number: MFCD03838856
• UNSPSC Code: 12352300
• PubChem Substance ID: 329761636
• NACRES: NA.22

Properties

• assay: 90%
• form: solid
• reaction suitability: reagent type: ligand
• mp: 105-109 °C
• SMILES string: CC(C)c1cccc(C(C)C)c1\N=C\C=N\c2c(cccc2C(C)C)C(C)C
• InChI: 1S/C26H36N2/c1-17(2)21-11-9-12-22(18(3)4)25(21)27-15-16-28-26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3/b27-15+,28-16+
• InChI key: JWVIIGXMTONOFR-DPCVLPDWSA-N

Description

Application

• Reactant in preparation of derived ruthenium olefin metathesis catalysts
• N-cyclic carbene ligand

Catalyst in:

• Palladium-catalyzed aerobic alc. oxidn. supported by a-diimine ligands
• Regioselective alkylation in presence of ruthenium-bisimine catalytic precursors
• N-arylation of aromatic amines
• Preparation of ruthenium nitrosyl alpha-diimine and iminoketone complexes as catalysts for transfer hydrogenation of ketones and atom transfer radical polymerization reactions

Safety Information

• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable