683159

Chiralyst P468

Umicore

• Synonym(s): Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, Bis(1,5-cyclooctadiene)rhodium triflate
• Empirical Formula (Hill Notation): C₁₇H₂₄F₃O₃RhS
• CAS Number: 99326-34-8
• Molecular Weight: 468.34
• MDL number: MFCD00143752
• UNSPSC Code: 12161600
• PubChem Substance ID: 329760799
• NACRES: NA.22

Properties

• form: powder
• reaction suitability: core: rhodium; reagent type: catalyst
• mp: 159 °C (dec. literature value) (lit.); 83-97 °C (dec. experimental value)
• SMILES string: [Rh+].[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2
• InChI: 1S/2C8H12.CHF3O3S.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h2*1-2,7-8H,3-6H2;(H,5,6,7);/q;;;+1/p-1/b2*2-1-,8-7-;;
• InChI key: GOPBTCMAUMSOBX-QMDOQEJBSA-M

Description

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H319
• pcodes: P264 - P280 - P305 + P351 + P338 - P337 + P313
• Hazard Classifications: Eye Irrit. 2
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves