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521892

Sigma-Aldrich

6-Methoxy-2-naphthaleneboronic acid

≥95%

Synonym(s):

6-Methoxy-2-naphthalenylboronic acid, 6-Methoxy-2-naphthylboronic acid, 6-Methoxynaphthalene-2-boronic acid

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About This Item

Linear Formula:
C10H6OCH3B(OH)2
CAS Number:
Molecular Weight:
202.01
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
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assay

≥95%

mp

>295 °C (lit.)

SMILES string

COc1ccc2cc(ccc2c1)B(O)O

InChI

1S/C11H11BO3/c1-15-11-5-3-8-6-10(12(13)14)4-2-9(8)7-11/h2-7,13-14H,1H3

InChI key

GZFAVYWCPSMLCM-UHFFFAOYSA-N

General description

Contains varying amounts of anhydride.

Application

Reactant for:
  • Suzuki-Miyaura coupling
  • Enantioselective a-arylation of carbonyls via copper-bisoxazoline catalysis
  • Enantioselective synthesis of aryl ketones
  • Copper-catalyzed trifluoromethylation
  • Rhodium-catalyzed oxidative coupling with alkynes

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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