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Sigma-Aldrich

Silver trifluoroacetate

≥99.99% trace metals basis

Synonym(s):

Trifluoroacetic acid silver salt

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About This Item

Linear Formula:
CF3COOAg
CAS Number:
Molecular Weight:
220.88
Beilstein/REAXYS Number:
3634022
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

assay

≥99.99% trace metals basis

form

crystalline powder
powder, crystals or chunks

reaction suitability

core: silver

mp

257-260 °C (dec.) (lit.)

SMILES string

FC(F)(F)C(=O)O[Ag]

InChI

1S/C2HF3O2.Ag/c3-2(4,5)1(6)7;/h(H,6,7);/q;+1/p-1

InChI key

KZJPVUDYAMEDRM-UHFFFAOYSA-M

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General description

Silver trifluoroacetate is a versatile reagent used in organic synthetic reactions, including acylation, alkylation, and cyclization reactions. It is also used to fabricate silver nanomaterials.

Application

Silver trifluoroacetate can be used:
  • As a precursor to synthesize silver nanoparticles.
  • As a starting material to fabricate conducting silver networks with high transmittance and low resistance via a polymer-assisted electrospinning technique.
  • As a reagent to prepare polynuclear luminescent complexes.
  • As a bifunctional reagent for oxidative carbonylative [4 + 1] annulation of aromatic acid.

pictograms

Skull and crossbonesEnvironment

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

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Direct Synthesis of Narrowly Dispersed Silver Nanoparticles Using a Single-Source Precursor
Xue Zhang Lin, et al.
Langmuir, 19, 10081-10085 (2003)
Silver trifluoroacetate as a bifunctional reagent for palladium-catalyzed oxidative carbonylative [4+ 1] annulation of aromatic acids
Zhuang-Zhuang Li, et al
Organic Chemistry Frontiers : An International Journal of Organic Chemistry / Royal Society of Chemistry, 10, 2243-2250 (2023)
Perhalophenyl(tetrahydrothiophene)gold(I) Complexes as Lewis Bases in Acid?Base Reactions with Silver Trifluoroacetate
Eduardo J. Fernandez, et al.},
Organometallics, 26, 5931-5939 (2007)
Conducting Silver Networks Based on Electrospun Poly(Methyl Methacrylate) and Silver Trifluoroacetate
Hung-Tao Chen, et al.
ACS Applied Materials & Interfaces, 7, 9479-9485 (2015)

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