467839

Bismuth(III) nitrate pentahydrate

≥99.99% trace metals basis

• Synonym(s): Bismuth trinitrate pentahydrate
• Linear Formula: Bi(NO₃)₃ · 5H₂O
• CAS Number: 10035-06-0
• Molecular Weight: 485.07
• EC Number: 233-791-8
• UNSPSC Code: 12161600
• PubChem Substance ID: 24870440
• NACRES: NA.22

Properties

• assay: ≥99.99% trace metals basis
• form: solid
• reaction suitability: core: bismuth; reagent type: catalyst
• impurities: ≤0.005% insolubles; <100 ppm total metallic impurities
• bp: 75-80 °C (lit.)
• mp: 30 °C (lit.)
• anion traces: chloride (Cl^-): ≤0.001%; sulfate (SO₄^2-): ≤0.005%
• cation traces: Ag: ≤0.001%; As: ≤0.001%; Ca: ≤0.005%; Cu: ≤0.002%; Fe: ≤0.001%; K: ≤0.01%; Na: ≤0.02%; Pb: ≤0.002%
• SMILES string: O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C
• InChI: 1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1
• InChI key: DPLOIMSBRDLLRI-UHFFFAOYSA-N

Description

Application

An excellent oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. Convenient reagent for selective oxidation of sufides to sulfoxides.

Safety Information

• pictograms: GHS03,GHS05
• signalword: Danger
• hcodes: H272,H318
• pcodes: P210 - P220 - P280 - P305 + P351 + P338 - P370 + P378 - P501
• Hazard Classifications: Eye Dam. 1 - Ox. Sol. 2
• Storage Class: 5.1B - Oxidizing hazardous materials
• wgk_germany: WGK 2
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges