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420107

Sigma-Aldrich

Bromotris(dimethylamino)phosphonium hexafluorophosphate

98%

Synonym(s):

BroP, Bromotris(N-methylmethanaminato)-phosphorus hexafluorophosphate

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About This Item

Linear Formula:
BrP[N(CH3)2]3PF6
CAS Number:
50296-37-2
Molecular Weight:
388.07
MDL number:
MFCD00191864
UNSPSC Code:
12352101
PubChem Substance ID:
24866311

assay

98%

reaction suitability

reaction type: Coupling Reactions

mp

>300 °C (lit.)

application(s)

peptide synthesis

SMILES string

F[P-](F)(F)(F)(F)F.CN(C)[P+](Br)(N(C)C)N(C)C

InChI

1S/C6H18BrN3P.F6P/c1-8(2)11(7,9(3)4)10(5)6;1-7(2,3,4,5)6/h1-6H3;/q+1;-1

InChI key

XELPBWPBGHCIKX-UHFFFAOYSA-N

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Application

Reagent for:
Conjugate addition of nitroalkanes to an acrylate equivalent
A novel polymer supported approach to nucleoside modification
Asymmetric hydrogenations
Peptide coupling
Pyrrolidine hydroxylation
Synthesis of cyclic PNA-based compound directed against HIV-1 TAR RNA

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

pictograms

Health hazardCorrosion
GHS08,GHS05

signalword

Danger

hcodes

H314,H350

Hazard Classifications

Carc. 1B - Skin Corr. 1B

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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