419206
Benzyl(triphenylphosphoranylidene)acetate
97%
Synonym(s):
(Benzyloxycarbonylmethylene)triphenylphosphorane, 2-(Triphenylphosphoranylidene)acetic acid phenylmethyl ester
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About This Item
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assay
97%
reaction suitability
reaction type: C-C Bond Formation
mp
120-122 °C (lit.)
functional group
ester
phenyl
phosphine
SMILES string
O=C(OCc1ccccc1)C=P(c2ccccc2)(c3ccccc3)c4ccccc4
InChI
1S/C27H23O2P/c28-27(29-21-23-13-5-1-6-14-23)22-30(24-15-7-2-8-16-24,25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20,22H,21H2
InChI key
INKMLGJBBDRIQR-UHFFFAOYSA-N
Related Categories
1 of 4
This Item | 157929 | 369799 | 376876 |
|---|---|---|---|
| reaction suitability reaction type: C-C Bond Formation | reaction suitability reaction type: C-C Bond Formation | reaction suitability reaction type: C-C Bond Formation | reaction suitability reaction type: C-C Bond Formation |
| mp 120-122 °C (lit.) | mp 168-172 °C (lit.) | mp 152-155 °C (lit.) | mp 173-175 °C (lit.) |
| functional group ester | functional group ester, phosphine | functional group ester, phosphine | functional group amine, phosphine |
Application
- Tributylphosphine-mediated vinylogous Wittig reactions
- Synthesis of 1,2-dioxanes for antitrypanosomal activity
- Organocatalytic Michael-type reactions / Wittig reactions of phosphorus ylides and unsaturated ketones
- Stereoselective phosphine-catalyzed cycloaddition to form spirocyclopenteneoxindoles
- Enantioselective synthesis of pantothenic acid
- Preparation of phosphorus ylides from phosphoranes and acetic anhydride
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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