41566

(2R,5R)-(−)-trans-2,5-Dimethylpyrrolidine

≥97.0% (GC)

• Empirical Formula (Hill Notation): C₆H₁₃N
• CAS Number: 62617-70-3
• Molecular Weight: 99.17
• Beilstein/REAXYS Number: 4652641
• MDL number: MFCD01863020
• UNSPSC Code: 12352005
• PubChem Substance ID: 57650066

Properties

• assay: ≥97.0% (GC)
• optical activity: [α]20/D −19.0±1.5°, c = 2% in methylene chloride
• refractive index: n20/D 1.431
• density: 0.852 g/mL at 20 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: C[C@@H]1CC[C@@H](C)N1
• InChI: 1S/C6H13N/c1-5-3-4-6(2)7-5/h5-7H,3-4H2,1-2H3/t5-,6-/m1/s1
• InChI key: ZEBFPAXSQXIPNF-PHDIDXHHSA-N

Description

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Important chiral auxiliary with a pseudo C₂ axis; diastereoselective alkylation of ketone enamines [1]; Highly stereoselective addition reactions of the enamine of β-keto esters (vinylogous urethanes) [2]; Radical reactions of unsaturated amides[3]

Safety Information

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H302,H314
• pcodes: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Flam. Liq. 2 - Skin Corr. 1B
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 44.6 °F - closed cup
• flash_point_c: 7.0 °C - closed cup
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter