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409618

Sigma-Aldrich

Bis[bis(trimethylsilyl)amino]tin(II)

Synonym(s):

Bis(bis(trimethylsilyl)amino)stannylene, Tin bis[bis(trimethylsilyl)amide], Tin(II) bis(hexamethyldisilazide)

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About This Item

Linear Formula:
[[(CH3)3Si]2N]2Sn
CAS Number:
Molecular Weight:
439.48
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

form

liquid

reaction suitability

core: tin

refractive index

n20/D 1.514 (lit.)

bp

112 °C/0.05 mmHg (lit.)

mp

37-38 °C (lit.)

density

1.136 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C[Si](C)(C)N([SnH2]N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

InChI

1S/2C6H18NSi2.Sn/c2*1-8(2,3)7-9(4,5)6;/h2*1-6H3;/q2*-1;+2

InChI key

WLNIUEYAQZRJFS-UHFFFAOYSA-N

Application

Reagent for the conversion of aldehydes and ketones to N,N-dialkyleneamines.

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

132.8 °F - closed cup

flash_point_c

56 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

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The Journal of Organic Chemistry, 57, 5063-5063 (1992)
Synlett, 131-131 (1993)

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