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Sigma-Aldrich

Pentadecafluorotriethylamine

96%

Synonym(s):

Perfluorotriethylamine, Tris(pentafluoroethyl)amine

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About This Item

Linear Formula:
N(CF2CF3)3
CAS Number:
359-70-6
Molecular Weight:
371.05
Beilstein/REAXYS Number:
1813672
EC Number:
206-632-5
MDL number:
MFCD00166270
UNSPSC Code:
12352100
PubChem Substance ID:
24864686

vapor pressure

2.15 psi ( 20 °C)

assay

96%

refractive index

n20/D 1.262 (lit.)

bp

68-69 °C/743 mmHg (lit.)

density

1.736 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(F)(F)N(C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)F

InChI

1S/C6F15N/c7-1(8,9)4(16,17)22(5(18,19)2(10,11)12)6(20,21)3(13,14)15

InChI key

CBEFDCMSEZEGCX-UHFFFAOYSA-N

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General description

Pentadecafluorotriethylamine (Perfluorotriethylamine, Tris(pentafluoroethyl)amine) is a non-polar organo fluorine compound. Its various physical parameters have been reported. It is an efficient substitute of reaction medium for the Lewis acid mediated reactions. Pyrolysis of perfluorotriethylamine was studied to investigate its thermal behavior in firefighting. Perfluorinated N-ethylpyrrolidine has been identified as the major decomposition product by GC-MS analysis. Production of long-lived microbubbles (50-100μm) in perfluorotriethylamine has been studied.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Thermal decomposition of halon alternatives.
Yamamoto T, et al.
Chemosphere, 35(3), 643-654 (1997)
An efficient high-yield synthesis for perfluorinated tertiary alkyl amines.
Felling KW and Lagow RJ.
Journal of Fluorine Chemistry, 123(2), 233-236 (2003)
Organic reactions without an organic medium. Utilization of perfluorotriethylamine as a reaction medium.
Nakano H and Kitazume T.
Green Chemistry, 1(1), 21-22 (1999)
The behavior of bubbles in perfluorotriethylamine under the effect of strong electric fields.
Korobeinikov SM, et al.
High Temperature, 39(6), 821-825 (2001)

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