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363715

Sigma-Aldrich

2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine vanadium(IV) oxide

95%

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About This Item

Empirical Formula (Hill Notation):
C36H44N4OV
CAS Number:
27860-55-5
Molecular Weight:
599.70
MDL number:
MFCD00058868
UNSPSC Code:
12352103
PubChem Substance ID:
24862212
NACRES:
NA.23

assay

95%

form

powder

reaction suitability

reagent type: catalyst
core: vanadium

λmax

407 nm
571 nm (2nd)

SMILES string

CCc1c(CC)c2cc3c(CC)c(CC)c4cc5nc(cc6c(CC)c(CC)c(cc1n2)n6[V](=O)n34)c(CC)c5CC

InChI

1S/C36H44N4.O.V/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;;/h17-20H,9-16H2,1-8H3;;/q-2;;+2/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;;

InChI key

XIJDRZKWTNMUAR-YAJYDHHFSA-N

General description

Self assembled monolayers of 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine vanadium(IV) oxide on highly oriented pyretic graphite (HOPG) was studied by scanning tunneling microscopy. It can be used as a starting material in the preparation of the π-cation radical derivative [VO(OH)2(OEP•)]SbCl6.

Features and Benefits

Starting material in the preparation of the π-cation radical derivative [VO(OH)2(OEP•)]SbCl6.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

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Scanning tunneling microscopy investigation of vanadyl and cobalt(II) octaethylporphyrin self-assembled monolayer arrays on graphite
Miyake Y, et al.
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 313-314, 230-233 (2008)

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