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359823

Sigma-Aldrich

Chromic acid, polymer-supported

macroporous, 20-50 mesh, extent of labeling: ~2.5 mmol/g loading

Synonym(s):

Chromic acid on Amberlyst® A-26

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About This Item

MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.22

form

macroporous

composition

Carbon content, 43.0-54.0%

reaction suitability

reaction type: solution phase peptide synthesis
reactivity: alcohol reactive

extent of labeling

~2.5 mmol/g loading

particle size

20-50 mesh

SMILES string

O=[Cr](=O)=O

InChI

1S/Cr.3O

InChI key

WGLPBDUCMAPZCE-UHFFFAOYSA-N

Application

Polymer-supported reagent for the clean oxidation of primary and secondary alcohols to carbonyl compounds in high yields.

Legal Information

Amberlyst is a registered trademark of The Dow Chemical Company or an affiliated company of Dow

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Muta. 1B - Ox. Sol. 2 - Repr. 2 - Resp. Sens. 1 - Skin Corr. 1A - Skin Sens. 1 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges


Certificates of Analysis (COA)

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Cardillo, G.
Tetrahedron Letters, 3985-3985 (1976)
L.G. Wade et al.
Journal of Chemical Education, 57, 438-438 (1980)
G. Cainelli et al.
Journal of the American Chemical Society, 98, 6737-6737 (1976)

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