347019

(−)-(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyl methyl ether

98%

• Empirical Formula (Hill Notation): C₂₅H₁₈FeOP
• CAS Number: 82863-72-7
• Molecular Weight: 421.23
• MDL number: MFCD00075375
• UNSPSC Code: 12352103

Properties

• assay: 98%
• optical activity: [α]20/D −337°, c = 1 in chloroform
• mp: 127-128 °C (lit.)
• SMILES string: [Fe].[CH]1[CH][CH][CH][CH]1.CO[C@H](C)[C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4

Description

Application

Ligand for the synthesis of optically active binaphthyls, and ternaphthalenes via asymmetric Grignard cross-coupling.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302 + H312 + H332
• pcodes: P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves