337242

4-Fluoro-3-methylanisole

97%

• Linear Formula: FC₆H₃(CH₃)OCH₃
• CAS Number: 2338-54-7
• Molecular Weight: 140.15
• MDL number: MFCD00042293
• UNSPSC Code: 12352100
• PubChem Substance ID: 24860467
• NACRES: NA.22

Properties

• assay: 97%
• refractive index: n20/D 1.492 (lit.)
• bp: 174-175 °C/762 mmHg (lit.)
• density: 1.07 g/mL at 25 °C (lit.)
• SMILES string: COc1ccc(F)c(C)c1
• InChI: 1S/C8H9FO/c1-6-5-7(10-2)3-4-8(6)9/h3-5H,1-2H3
• InChI key: XZBXPBDJLUJLEU-UHFFFAOYSA-N

Description

General description

Photolysis of the charge transfer complex of tetranitromethane and 4-fluoro-3-methylanisole in dichloromethane at -20°C yields the epimeric 1-fluoro-4-methoxy-6-methyl-6-nitro-3-trinitromethylcyclo-hexa-1,4-dienes, 1-fluoro-4-methoxy-2-methyl-r-5-nitro-c-6-trinitromethylcyclohexa-1,3-diene and 4-fluoro-5-methyl-2-trinitromethylanisole.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: 145.4 °F - closed cup
• flash_point_c: 63 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter