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308099

Sigma-Aldrich

N,N-Diethyl-N′-methylethylenediamine

97%

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About This Item

Linear Formula:
(C2H5)2NCH2CH2NHCH3
CAS Number:
104-79-0
Molecular Weight:
130.23
EC Number:
203-238-5
MDL number:
MFCD00009053
UNSPSC Code:
12352100
PubChem Substance ID:
24858647
NACRES:
NA.22

assay

97%

form

liquid

refractive index

n20/D 1.4296 (lit.)

bp

157-160 °C (lit.)

density

0.805 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CCN(CC)CCNC

InChI

1S/C7H18N2/c1-4-9(5-2)7-6-8-3/h8H,4-7H2,1-3H3

InChI key

MKDYQLJYEBWUIG-UHFFFAOYSA-N

General description

The Michael addition of N,N-Diethyl-N′-methylethylenediamine to nocathiacin was studied[1].

Application

N,N-Diethyl-N′-methylethylenediamine was used as a derivatization agent in the quantitative determination of isocyanates by capillary electrophoresis with tris(2,2′-bipyridyl)ruthenium(II) electrochemiluminescence (ECL)[2].

pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

hcodes

H226,H314

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

105.8 °F - closed cup

flash_point_c

41 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
001401292V
0001401292
10131JJ
06422LS
05814KR

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Haijuan Li et al.
Electrophoresis, 30(22), 3926-3931 (2009-11-04)
CE with tris(2,2'-bipyridyl) ruthenium(II) (Ru(bpy)(3) (2+)) electrochemiluminescence (ECL) detection for the quantitative determination of isocyanates was first reported. Hexamethylene diisocyanate (HDI) and hexyl isocyanate (HI) were used as the model analytes. Commercially available N,N-diethyl-N'-methylethylenediamine was used as the derivatization reagent.
Organic reactions in frozen water: Michael addition of amines and thiols to the dehydroalanine side chain of nocathiacins.
Tetrahedron Letters, 45(5), 1059-1063 null

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