300837

Methyl chlorodifluoroacetate

99%

• Linear Formula: ClF₂CCOOCH₃
• CAS Number: 1514-87-0
• Molecular Weight: 144.50
• Beilstein/REAXYS Number: 1756072
• EC Number: 216-154-9
• MDL number: MFCD00000775
• UNSPSC Code: 12352100
• PubChem Substance ID: 24858108
• NACRES: NA.22

Properties

• assay: 99%
• form: liquid
• refractive index: n20/D 1.349 (lit.)
• bp: 79-81 °C (lit.)
• density: 1.37 g/mL at 25 °C (lit.)
• SMILES string: COC(=O)C(F)(F)Cl
• InChI: 1S/C3H3ClF2O2/c1-8-2(7)3(4,5)6/h1H3
• InChI key: AWUPLMYXZJKHEG-UHFFFAOYSA-N

Description

General description

Methyl chlorodifluoroacetate is a trifluoromethylating agent.

Application

Methyl chlorodifluoroacetate was used in preparation of 2,2-difluoro-3-hydroxyesters and gem-difluorocyclopropane.

Safety Information

• pictograms: GHS02,GHS05
• signalword: Danger
• hcodes: H225,H314
• pcodes: P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Flam. Liq. 2 - Skin Corr. 1B
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 66.2 °F - closed cup
• flash_point_c: 19 °C - closed cup
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter