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300438

Sigma-Aldrich

(2R)-(−)-Glycidyl 4-nitrobenzoate

98%

Synonym(s):

(R)-(−)-Glycidyl 4-nitrobenzoate, (R)-(−)-Oxirane-2-methanol 4-nitrobenzoate

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About This Item

Empirical Formula (Hill Notation):
C10H9NO5
CAS Number:
Molecular Weight:
223.18
Beilstein/REAXYS Number:
5278590
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

assay

98%

form

solid

optical activity

[α]19/D −37°, c = 1.08 in chloroform

mp

60-62 °C (lit.)

functional group

ester
ether
nitro

storage temp.

2-8°C

SMILES string

[O-][N+](=O)c1ccc(cc1)C(=O)OC[C@H]2CO2

InChI

1S/C10H9NO5/c12-10(16-6-9-5-15-9)7-1-3-8(4-2-7)11(13)14/h1-4,9H,5-6H2/t9-/m1/s1

InChI key

MUWIANZPEBMVHH-SECBINFHSA-N

Application

(2R)-(−)-Glycidyl 4-nitrobenzoate can be used as a starting material in the total synthesis of leukotriene B4.[1]

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Total synthesis of leukotriene B4.
Kerdesky FAJ, et al.
The Journal of Organic Chemistry, 58(13), 3516-3520 (1993)

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