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Sigma-Aldrich

Methyl trans-3-(4-methoxyphenyl)glycidate

97%

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About This Item

Empirical Formula (Hill Notation):
C11H12O4
CAS Number:
42245-42-1
Molecular Weight:
208.21
EC Number:
255-735-1
MDL number:
MFCD00012316
UNSPSC Code:
12162002
PubChem Substance ID:
24857951
NACRES:
NA.23

assay

97%

mp

69-71 °C (lit.)

SMILES string

COC(=O)[C@H]1O[C@@H]1c2ccc(OC)cc2

InChI

1S/C11H12O4/c1-13-8-5-3-7(4-6-8)9-10(15-9)11(12)14-2/h3-6,9-10H,1-2H3/t9-,10+/m1/s1

InChI key

CVZUMGUZDAWOGA-ZJUUUORDSA-N

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Occupational contact dermatitis from trans-methyl-3-(4-methoxyphenyl)glycidate.
H Buisson et al.
Contact dermatitis, 25(4), 262-263 (1991-10-01)
Ritsuo Imashiro et al.
The Journal of organic chemistry, 68(3), 974-979 (2003-02-01)
An efficient synthesis of methyl (2R,3S)-3-(4-methoxyphenyl)glycidate (-)-2, a key intermediate for diltiazem (1), has been developed on the basis of the highly enantioselective Mukaiyama aldol reaction of p-anisaldehyde (4a) with alpha,alpha-dichloro ketene silyl acetal 5. Thus, the reaction using a
Y Yamada et al.
International archives of occupational and environmental health, 60(1), 7-14 (1988-01-01)
Forty-nine out of 54 male workers engaged in the production of an epoxy compound, t-methyl-3-phenylglycidate, showed skin symptoms in varying degrees that may be due to the skin-irritative effect of the compound. The exposed workers were also shown to have
Dermatitis from methyl 2,3 epoxy-3-(4-methoxyphenyl)propionate.
E Rudzki et al.
Contact dermatitis, 23(5), 382-382 (1990-11-01)
Li Gao et al.
Journal of industrial microbiology & biotechnology, 31(11), 525-530 (2004-11-19)
Lipase production and cell growth of Serratia marcescens ECU1010 were optimized in shake flasks, with lipase production being enhanced 9.5-fold (4,780 U/l) compared with the initial activity (500 U/l). Optimal carbon and nitrogen sources were Tween-80 and peptone, and the
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