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274542

Sigma-Aldrich

2-Bromo-2′-nitroacetophenone

99%

Synonym(s):

2′-Nitrophenacyl bromide

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About This Item

Linear Formula:
O2NC6H4COCH2Br
CAS Number:
6851-99-6
Molecular Weight:
244.04
MDL number:
MFCD00010294
UNSPSC Code:
12352100
PubChem Substance ID:
24856483
NACRES:
NA.22

assay

99%

mp

55-57 °C (lit.)

functional group

bromo
ketone
nitro

SMILES string

[O-][N+](=O)c1ccccc1C(=O)CBr

InChI

1S/C8H6BrNO3/c9-5-8(11)6-3-1-2-4-7(6)10(12)13/h1-4H,5H2

InChI key

SGXUUCSRVVSMGK-UHFFFAOYSA-N

Application

2-Bromo-2′-nitroacetophenone, an electroactive derivative-forming reagent, was used as a precolumn reagent for preparing prostaglandin derivatives[1].

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
0000070647
0000068084
1437556V
1421555
1437556

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G M Beck et al.
Talanta, 36(3), 373-377 (1989-03-01)
Conventional reversed-phase HPLC conditions have been optimized for resolution of a mixture containing prostaglandins PGE(1), PGE(2), PGF(1alpha), and PGF(2alpha). Electroactive derivative-forming reagents, such as p-nitrobenzyloxyamine, 2-bromo-2'-nitroacetophenone, and 2,4-dinitrophenylhydrazine have been evaluated for use as precolumn reagents for forming prostaglandin derivatives.

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