206067

Potassium hexachloroplatinate(IV)

reagent grade, 98%

• Synonym(s): Dipotassium hexachloroplatinate, Dipotassium platinum hexachloride, Platinic potassium chloride, Platinum potassium chloride, Potassium chloroplatinate, Potassium platinum(IV) chloride, Potassium platinum(IV) hexachloride
• Linear Formula: K₂PtCl₆
• CAS Number: 16921-30-5
• Molecular Weight: 485.99
• EC Number: 240-979-3
• MDL number: MFCD00011389
• UNSPSC Code: 12161600
• PubChem Substance ID: 24852373
• NACRES: NA.22

Properties

• grade: reagent grade
• assay: 98%
• reaction suitability: core: platinum; reagent type: catalyst
• mp: 250 °C (dec.) (lit.)
• SMILES string: [K+].[K+].Cl[Pt--](Cl)(Cl)(Cl)(Cl)Cl
• InChI: 1S/6ClH.2K.Pt/h6*1H;;;/q;;;;;;2*+1;+4/p-6
• InChI key: DPAIVKJGTXERIM-UHFFFAOYSA-H

Description

General description

Potassium hexachloroplatinate (K₂PtCl₆) is the inorganic compound that is commonly used as a platinum (Pt) precursor for the preparation of platinum-based compounds.

Application

Potassium hexachloroplatinate (K₂PtCl₆) can be used to synthesize:

• K₂PtCl₆-PEG/SiO₂ complex catalytic system for vapor-phase hydrosilylation reaction.
• Pt-decorated nickel pyrophosphate β-Ni₂P₂O₇/Pt and nickel phosphate Ni₃(PO₄)₂/Pt catalysts for the hydrogen evolution reaction (HER) by water splitting.
• Polypyrrole-platinum complex sphere catalyst for the decomposition of hydrogen peroxide to form oxygen.

For small scale and high throughput uses, product is also available as ChemBeads (932175)

Safety Information

• pictograms: GHS06,GHS08,GHS05,GHS09
• signalword: Danger
• hcodes: H290,H301,H317,H318,H334,H372,H410
• pcodes: P234 - P273 - P280 - P301 + P310 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1
• Storage Class: 6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• wgk_germany: WGK 1
• flash_point_f: does not flash
• flash_point_c: does not flash
• ppe: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges