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195936

Sigma-Aldrich

3-(Perfluorobutyryl)-(+)-camphor

96%

Synonym(s):

(+)-3-(Heptafluorobutyryl)-(+)-camphor, 3-(Perfluorobutyryl)-D-camphor

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About This Item

Empirical Formula (Hill Notation):
C14H15F7O2
CAS Number:
51800-99-8
Molecular Weight:
348.26
Beilstein/REAXYS Number:
2306496
EC Number:
257-430-9
MDL number:
MFCD00064154
UNSPSC Code:
12352115
PubChem Substance ID:
24851726
NACRES:
NA.22

assay

96%

optical activity

[α]20/D +125°, c = 2.6 in chloroform

refractive index

n20/D 1.421 (lit.)

bp

60-70 °C/0.2 mmHg (lit.)

density

1.218 g/mL at 25 °C (lit.)

SMILES string

CC1(C)C2CC[C@@]1(C)C(=O)C2C(=O)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C14H15F7O2/c1-10(2)6-4-5-11(10,3)8(22)7(6)9(23)12(15,16)13(17,18)14(19,20)21/h6-7H,4-5H2,1-3H3/t6-,7?,11+/m1/s1

InChI key

PEWOESYEGLBLNR-XGLFCGLISA-N

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Application

3-(Perfluorobutyryl)-(+)-camphor can be used:
  • As a ligand in the synthesis of chiral europium complex for optoelectronic and photonic applications.
  • As a ligand in the preparation of sodium tetrakis(3-heptafluorobutylryl-(+)-camphorato) Ln(III) complexes applicable as chemical sensors and NMR shift reagents.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

199.4 °F - closed cup

flash_point_c

93 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

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Highly circularly polarized electroluminescence from a chiral europium complex
Zinna F, et al.
Advanced Materials, 27(10), 1791-1795 (2015)
Novel Configurational Structures of Sodium Tetrakis (3-heptafluorobutylryl-(+)-camphorato) Ln (III) Complexes with a Trapped Na+ by Na+?FC Interactions in the Solid State and in Solution
Shirotani D, et al.
Inorganic Chemistry, 45(16), 6111-6113 (2006)

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