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176230

Sigma-Aldrich

Triethyloxonium tetrafluoroborate solution

1.0 M in methylene chloride

Synonym(s):

Et3OBF4, Meerwein′s reagent, Triethyloxonium fluoroborate

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100 ML
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100 ML
$149.00

About This Item

Linear Formula:
(C2H5)3O(BF4)
CAS Number:
Molecular Weight:
189.99
Beilstein/REAXYS Number:
3598090
MDL number:
UNSPSC Code:
12352001
PubChem Substance ID:
NACRES:
NA.22

$149.00


Available to ship onApril 22, 2025Details


Request a Bulk Order

Quality Level

concentration

1.0 M in methylene chloride

density

1.328 g/mL at 25 °C

functional group

ether

storage temp.

2-8°C

SMILES string

F[B-](F)(F)F.CC[O+](CC)CC

InChI

1S/C6H15O.BF4/c1-4-7(5-2)6-3;2-1(3,4)5/h4-6H2,1-3H3;/q+1;-1

InChI key

IYDQMLLDOVRSJJ-UHFFFAOYSA-N

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Application

Used in the preparation of ω-aminoesters from lactams.[1]

signalword

Danger

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system

supp_hazards

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Synthetic Communications, 18, 1625-1625 (1988)
Some detoxification methods for N-nitrosamine-contaminated wastes.
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IARC scientific publications, (41)(41), 151-157 (1982-01-01)
J Aguado et al.
Biotechnology and applied biochemistry, 17 ( Pt 1), 49-55 (1993-02-01)
beta-Glucosidase from Penicillium funiculosum was immobilized on nylon powder previously activated with triethyloxonium tetrafluoroborate, 1,2-diaminoethane and glutaraldehyde. The activation of the nylon powder and the immobilization processes were studied and optimized for the enzyme and the matrix. A high activity
R Ben Avraham et al.
FEBS letters, 180(2), 239-242 (1985-01-28)
Treatment of trypsin with triethyloxonium tetrafluoroborate at pH 8, 25 degrees C, results in abolition of binding to the enzyme of specific cationic substrates and inhibitors. The binding constant of soybean trypsin inhibitor to ethylated trypsin is 10000-fold smaller than
Itedale Namro Redwan et al.
The Journal of organic chemistry, 77(16), 7071-7075 (2012-07-20)
This note describes a rapid and mild strategy for the loading of alcohols and anilines onto a polystyrene triphenylmethyl (trityl) resin. High loadings were obtained in a matter of minutes by treating resin-bound trityl chloride with triethyloxonium tetrafluoroborate followed by

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