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assay
95%
refractive index
n20/D 1.434 (lit.)
bp
125-128 °C (lit.)
density
0.895 g/mL at 25 °C (lit.)
SMILES string
CC(=O)C1(C)CC1
InChI
1S/C6H10O/c1-5(7)6(2)3-4-6/h3-4H2,1-2H3
InChI key
OQBCJXUAQQMTRW-UHFFFAOYSA-N
General description
Methyl 1-methylcyclopropyl ketone undergoes samarium diiodide induced coupling to form 6-Hydroxy-3-methyl-6-(1-methylcyclopropyl)heptan-2-one.
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Samarium Diiodide Induced Reactions of Cyclopropyl Ketones: Reductive Ring Cleavage and Dimerization Leading to 1, 8-Diketones-Scope, Limitations, Mechanisms.
European Journal of Organic Chemistry, 2006(7), 1733-1739 (2006)
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