Yoon Group – Prof. Product Portal
Professor Tehshik Yoon
One major theme of research in the Yoon Lab is the development of unique chemical transformations enabled by visible light photochemistry. A variety of transition metal photocatalysts responsive to visible light are known, and the Yoon Lab has shown that their well understood photochemistry can be coupled to cycloadditions, arene oxidations, amine functionalizations, and thiol-ene reactions, among others. An important feature of this strategy is the ability to use rational ligand modifications to tune the photophysical and electrochemical properties of the catalyst, exemplified by the complexes below.
Recent papers from the Yoon Group
1.
Lu Z, Yoon TP. 2012. Visible Light Photocatalysis of [2+2] Styrene Cycloadditions by Energy Transfer. Angew. Chem. Int. Ed.. 51(41):10329-10332. https://doi.org/10.1002/anie.201204835
2.
Lin S, Ischay MA, Fry CG, Yoon TP. 2011. Radical Cation Diels?Alder Cycloadditions by Visible Light Photocatalysis. J. Am. Chem. Soc.. 133(48):19350-19353. https://doi.org/10.1021/ja2093579
3.
Ischay MA, Anzovino ME, Du J, Yoon TP. 2008. Efficient Visible Light Photocatalysis of [2+2] Enone Cycloadditions. J. Am. Chem. Soc.. 130(39):12886-12887. https://doi.org/10.1021/ja805387f
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DISCIPLINES
- Organic Synthetic Chemistry
- Catalysis
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