901138
14-Azido-3,6,9,12-tetraoxatetradecan-1-amine
Synonym(s):
2-[2-[2-[2-(2-Azidoethoxy)ethoxy]ethoxy]ethoxy]ethanamine
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About This Item
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form
liquid
Quality Level
reaction suitability
reagent type: linker
refractive index
n/D 1.45
density
1.10 g/mL
functional group
amine
azide
storage temp.
2-8°C
SMILES string
NCCOCCOCCOCCOCCN=[N+]=[N-]
InChI
1S/C10H22N4O4/c11-1-3-15-5-7-17-9-10-18-8-6-16-4-2-13-14-12/h1-11H2
InChI key
ZMBGKXBIVYXREN-UHFFFAOYSA-N
Related Categories
Application
14-Azido-3,6,9,12-tetraoxatetradecan-1-amine is an azide with polyethylene glycol-like characteristics that can be used to prepare fluorescent polymer particles via enzymatic miniemulsion polymerization and copper (I) catalyzed click reaction approach. It is also used as a reactant to synthesize α-aryl-α-diazoamides by aminolysis of N-succinimidyl α-aryl-α-diazoacetates.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
230.0 °F
Flash Point(C)
110 °C
Certificates of Analysis (COA)
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A green approach for the synthesis of fluorescent polymer particles by combined use of enzymatic miniemulsion polymerization with clickable surfmer and click reaction
Transactions of the Materials Research Society of Japan, 39(1), 57-60 (2014)
Organic letters, 23(8), 3110-3114 (2021-04-06)
α-Aryl-α-diazoamides were synthesized in two steps under mild conditions. This expeditious route employs Pd-catalyzed C-H arylation of N-succinimidyl 2-diazoacetate to obtain N-succinimidyl 2-aryl-2-diazoacetates, followed by aminolysis. The ensuing diazo compounds can esterify carboxyl groups in aqueous solution, and the ester
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