668001

Silver bis(trifluoromethanesulfonyl)imide

97%

• Synonym(s): Silver bis(trifluoromethanesulfonyl)amide, Silver bis(trifluoromethylsulfonyl)amide, Silver triflimide
• Empirical Formula (Hill Notation): C₂AgF₆NO₄S₂
• CAS Number: 189114-61-2
• Molecular Weight: 388.01
• MDL number: MFCD08457644
• UNSPSC Code: 12161600
• PubChem Substance ID: 24884953
• NACRES: NA.22

Properties

• Assay: 97%
• form: solid
• reaction suitability: core: silver; reagent type: catalyst
• mp: 248.8 °C
• SMILES string: FC(F)(F)S(=O)(=O)N([Ag])S(=O)(=O)C(F)(F)F
• InChI: 1S/C2F6NO4S2.Ag/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1
• InChI key: HSYLTRBDKXZSGS-UHFFFAOYSA-N

Description

General description

Silver bis(trifluoromethanesulfonyl)imide is a silver-based salt that is widely used as a catalyst in organic synthesis. It is used in the C₃ regioselective alkylation of indole derivatives via conjugated addition type reactions with α, β-enones. It is also used as a p-type dopant for efficient and stable solid-state dye-sensitized and perovskite solar cells.

Application

Gold Catalysts — 21st Century ′Gold Rush′

Safety Information

• Pictograms: GHS05
• Signal Word: Danger
• Hazard Statements: H314
• Precautionary Statements: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves